The Thermoanaerobium brockii alcohol dehydrogenase (TBADH) catalysed reduction of the racemic bicyclic ketone 5 gives epimeric alcohols derived from the same enantiomeric series, the reduction is enantioselective but not diastereoselective, an unusual result for a single enzyme.
D. R. Kelly and J. D. Lewis, J. Chem. Soc., Chem. Commun., 1991, 1330 DOI: 10.1039/C39910001330
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