Issue 12, 1991

Isolation and the IR spectra of chloro- and bromo-ethyl cations in cryogenic SbF5 matrices

Abstract

Reaction of MeCHCl2, CH2ClCH2Cl and CH2BrCH2Br respectively with SbF5 in a solid matrix at 77–200 K affords the most stable cations 2 and 3 as predicted by previously published high-level ab initio calculations.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 807-809

Isolation and the IR spectra of chloro- and bromo-ethyl cations in cryogenic SbF5 matrices

H. Vančik, K. Percač and D. E. Sunko, J. Chem. Soc., Chem. Commun., 1991, 807 DOI: 10.1039/C39910000807

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