Issue 10, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Confirmation of the H-bridged structure of the 2-butyl cation by comparison of experimental and ab initio IR frequencies

Peter Buzek,   Paul von Ragué Schleyer,   Stefan Sieber,   Wolfram Koch,   J. W. de M. Carneiro,   H. Vančik  and  D. E. Sunko  

Abstract

The IR spectrum of the 2-butyl cation, measured at –125 °C in an SbF5 matrix and calculated ab initio(MP2(FULL)/6-31G*), is characterized by a C(H [graphic omitted] ) C peak at 2175 cm–1 assigned to the nonclassical H-bridged (C2-symmetry) structure 1.

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Article information

DOI
https://doi.org/10.1039/C39910000671
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 671-674

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Confirmation of the H-bridged structure of the 2-butyl cation by comparison of experimental and ab initio IR frequencies

P. Buzek, P. von Ragué Schleyer, S. Sieber, W. Koch, J. W. de M. Carneiro, H. Vančik and D. E. Sunko, J. Chem. Soc., Chem. Commun., 1991, 671 DOI: 10.1039/C39910000671

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