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Issue 4, 1990
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Regioselective nucleophilic additions to tricarbonyl(η6-arene)chromium(0) complexes: electronic versus chelation control

Abstract

Regioselective addition of t-butyl-lithium to tricarbonyl(η6-benzyl alcohol)chromium(0) proceeds to give tricarbonyl(η6-5-methylene-6-exo-t-butylcyclohexa-1,3-diene)chromium(0), which can be isomerised to tricarbonyl(η6-o-t-butyltoluene)chromium(0). Repetition of the reaction on tricarbonyl(η6-1 -phenethanol)chromium(0) gives regio- and stereo-selectively the corresponding 5-ethylidene complex.

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Article type: Paper
DOI: 10.1039/P19900001133
Citation: J. Chem. Soc., Perkin Trans. 1, 1990,0, 1133-1144
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    Regioselective nucleophilic additions to tricarbonyl(η6-arene)chromium(0) complexes: electronic versus chelation control

    J. Blagg, S. G. Davies, C. L. Goodfellow and K. H. Sutton, J. Chem. Soc., Perkin Trans. 1, 1990, 0, 1133
    DOI: 10.1039/P19900001133

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