Issue 15, 1990

Synthesis and properties of binuclear [LTiCl2(µ-O)TiCl2L]n+(n= 0, 1, 2; L = 1,4,7-trimethyl-1,4,7-triazacyclononane) complexes. The crystal structure of the mixed valence compound [L2Ti2Cl4(µ-O)]Cl·2H2O

Abstract

Three linearly µ-oxo bridged binuclear complexes [L2Ti2Cl4(µ-O)]n+(n = 0,1,2) have been synthesized and the mixed valence complex [L2Ti2Cl4(µ-O)]Cl·2H2O has been characterized by X-ray crystallography (L = 1,4,7-trimethyl-1,4,7-triazacyclononane).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1042-1043

Synthesis and properties of binuclear [LTiCl2(µ-O)TiCl2L]n+(n= 0, 1, 2; L = 1,4,7-trimethyl-1,4,7-triazacyclononane) complexes. The crystal structure of the mixed valence compound [L2Ti2Cl4(µ-O)]Cl·2H2O

A. Bodner, B. S. P. C. D. Vedova, K. Wieghardt, B. Nuber and J. Weiss, J. Chem. Soc., Chem. Commun., 1990, 1042 DOI: 10.1039/C39900001042

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