Issue 7, 1990

Regio- and stereo-selective lithiation of diallyl amines: an easy entry to trianionic intermediates

Abstract

The successive treatment of diallyl amine (1a) with an alkyl-lithium reragent leads to several trianionic derivatives (4a) in a regio-and stereo-selective manner; in the case of N-allyl-N-(methylallyl)amine (1b), the lithiation step is only observed in the methylallyl moiety of the amine; these trianions are characterized by reaction with deuterium oxide to yeild the corresponding deuteriated products (5).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 587-588

Regio- and stereo-selective lithiation of diallyl amines: an easy entry to trianionic intermediates

J. Barluenga, F. Foubelo, R. González, F. J. Fañás and M. Yus, J. Chem. Soc., Chem. Commun., 1990, 587 DOI: 10.1039/C39900000587

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