The first synthesis of carbazomycins A and B (1) is described; the route involves Diels-Alder reaction of 1-methylpyrano[3,4-b]indol-3-one with ethyl 3-trimethylsilylpropynoate followed by functional group interconversions; the marine alkaloid hyellazole (2) was synthesized by a similar route.
C. J. Moody and P. Shah, J. Chem. Soc., Perkin Trans. 1, 1989, 376 DOI: 10.1039/P19890000376
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