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Issue 1, 1989
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Asymmetric synthesis of α-substituted o-methoxybenzyl alcohols via stereoselective additions to kinetically resolved o-anisaldehyde(tricarbonyl)chromium

Abstract

Homochiral (+)-o-anisaldehyde(tricarbonyl)chromium, prepared by a kinetic resolution procedure involving selective hydrolysis of the diastereoisomeric L-valinol derived imines, undergoes completely stereoselective addition reactions with methyl- and ethyl-magnesium iodide to give enantiomerically pure (–)-(S)-1-(o-methoxyphenyl)ethanol and (–)-(S)-1-(o-methoxyphenyl)propanol.

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Article type: Paper
DOI: 10.1039/P19890000192
Citation: J. Chem. Soc., Perkin Trans. 1, 1989,0, 192-194
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    Asymmetric synthesis of α-substituted o-methoxybenzyl alcohols via stereoselective additions to kinetically resolved o-anisaldehyde(tricarbonyl)chromium

    S. G. Davies and C. L. Goodfellow, J. Chem. Soc., Perkin Trans. 1, 1989, 0, 192
    DOI: 10.1039/P19890000192

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