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Issue 15, 1989
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Preparation and reactivity of η6-pyridine tricarbonyl chromium complexes

Abstract

Complexation of 2,6-bistrimethylsilylpyridine followed by desilylation generates η6-pyridinetricarbonylchromium which undergoes regioselective deprotonation-methylation to give 2-methylpyridinetricarbonylchromium and regio- and stereo-selective nucleophilic additions of alkyl-lithiums to generate, after methylation, N-methyl-exo-2-alkyl-1,2-dihydropyridinetricarbonylchromium complexes.

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Article type: Paper
DOI: 10.1039/C39890000995
Citation: J. Chem. Soc., Chem. Commun., 1989,0, 995-996
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    Preparation and reactivity of η6-pyridine tricarbonyl chromium complexes

    S. G. Davies and M. R. Shipton, J. Chem. Soc., Chem. Commun., 1989, 0, 995
    DOI: 10.1039/C39890000995

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