The N3O3 co-ordination sphere of (1b) and (1c) selectively stabilises low-spin FeII and FeIII in fac(2a) and mer(2b) geometries, respectively; mismatched combinations generated by rapid chemical/electrochemical electron transfer at low temperatures undergo spontaneous isomerisation at measurable rates to achieve equilibrium populations.
P. Basu, S. Pal and A. Chakravorty, J. Chem. Soc., Chem. Commun., 1989, 977 DOI: 10.1039/C39890000977
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...