Issue 7, 1988

Oxygen insertion into the metal–carbon bond of cyclopalladated 2-(alkylsulphinyl)azobenzenes by peracids. High yield regiospecific aromatic hydroxylation

Abstract

The title reaction occurs by an associative mechanism involving heterolytic O–O cleavage; the sequence azobenzene →(1)→(2)→ azophenol leading to overall regiospecific aromatic hydroxylation has been realised.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 468-470

Oxygen insertion into the metal–carbon bond of cyclopalladated 2-(alkylsulphinyl)azobenzenes by peracids. High yield regiospecific aromatic hydroxylation

C. R. Sinha, D. Bandyopadhyay and A. Chakravorty, J. Chem. Soc., Chem. Commun., 1988, 468 DOI: 10.1039/C39880000468

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements