Issue 4, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation and reactivity of 16-electron ‘half-sandwich’ ruthenium complexes; X-ray crystal structure of (η5-C5Me5)Ru(PPri3)Cl

Brian K. Campion,   Richard H. Heyn  and  T. Don Tilley  

Abstract

The new 16-electron ruthenium compounds (η5-C5Me5)Ru(L)Cl [(1), L = PPri3; (2), L = PCy3](Cy = cyclohexyl) were prepared from [(η5-C5Me5)RuCl]4 and PPri3 or PCy3, respectively, and the X-ray crystal structure of (1) has been determined; reactions of the title compounds with CO, C2H4, pyridine, and PhSiH3 are described.

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Article information

DOI
https://doi.org/10.1039/C39880000278
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 278-280

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Preparation and reactivity of 16-electron ‘half-sandwich’ ruthenium complexes; X-ray crystal structure of (η5-C5Me5)Ru(PPri3)Cl

B. K. Campion, R. H. Heyn and T. D. Tilley, J. Chem. Soc., Chem. Commun., 1988, 278 DOI: 10.1039/C39880000278

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