Decomposition of the tosylhydrazones (3), prepared from indole-2-carbaldehyde in two steps, gives the cyclopropapyrrolo[1,2-a]indoles (4), novel analogues of the mitomycin antitumour antibiotics, by an intramolecular cycloaddition reaction.
G. B. Jones and C. J. Moody, J. Chem. Soc., Chem. Commun., 1988, 166 DOI: 10.1039/C39880000166
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