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Issue 21, 1987
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Stereospecificity of the rearrangement of the α-alkoxy iron acyl [(η5-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph] to the α-metalla-ester [(η5-C5H5)Fe(CO)(PPh3)CH2CO2CH2Ph]

Abstract

The acid catalysed rearrangement of [(η5-C5H5)Fe(CO)(PPh3)COCH(R)OCH 2Ph](R = H, D, Me) to [(η5-C5H5)Fe(CO)(PPh3)CH(R)CO2CH2Ph] occurs stereospecifically with inversion of configuration at carbon.

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Article type: Paper
DOI: 10.1039/C39870001647
Citation: J. Chem. Soc., Chem. Commun., 1987,0, 1647-1648
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    Stereospecificity of the rearrangement of the α-alkoxy iron acyl [(η5-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph] to the α-metalla-ester [(η5-C5H5)Fe(CO)(PPh3)CH2CO2CH2Ph]

    S. G. Davies and M. Wills, J. Chem. Soc., Chem. Commun., 1987, 0, 1647
    DOI: 10.1039/C39870001647

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