Issue 11, 1987

Preparation of a novel optically active 8,8′-bi-isoquinolyl and its co-ordination as a bridging ligand in rhodium(I) complexes

Abstract

A novel optically active 7,7′-dimethoxy-8,8′-bi-isoquinolyl (5) with known absolute configuration has been prepared and has been found to co-ordinate to RhI as a bridging ligand in [RhCl(cod)]2[µ-(±)-(5)](6) and {Rh2(cod)2[µ-(+)-(5)]2}(CIO4)2(8)(cod = cyclo-octa-1,5-diene).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 807-809

Preparation of a novel optically active 8,8′-bi-isoquinolyl and its co-ordination as a bridging ligand in rhodium(I) complexes

K. Yamamoto, K. Watanabe, H. Chikamatsu, Y. Okamoto and T. Yoshida, J. Chem. Soc., Chem. Commun., 1987, 807 DOI: 10.1039/C39870000807

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