SCHEDULED MAINTENANCE
The η2-sila-acyl complex cp*Cl3Ta(η2-COSiMe3)(cp*=η5-C5Me5)(1) reacts rapidly with diphenyldiazomethane to form cp*Cl3[graphic omitted]CPh2}(2), the first characterized product of reaction between an η2-acyl compound and a diazoalkane.
J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib, J. Chem. Soc., Chem. Commun., 1987, 793 DOI: 10.1039/C39870000793
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