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Issue 16, 1986
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Regioselective nucleophilic additions to (η6-benzyl alcohol)tricarbonylchromium: isolation and X-ray crystal structure of the intermediate (η6-5-methylene-6-exo-t-butylcyclohexa-1,3-diene)tricarbonylchromium

Abstract

Treatment of (η6-benzyl alcohol)tricarbonylchromium with alkyl-lithium compounds (ButLi; MeLi-tetramethylethylenediamine; BunLi; PhLi) regioselectively generates the corresponding η6-5-methylene-6-exo-alkylcyclohexa-1,3-diene complexes which undergo proton catalysed isomerisations to give (η6-ortho-alkyltoluene)tricarbonylchromium complexes.

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Article type: Paper
DOI: 10.1039/C39860001283
Citation: J. Chem. Soc., Chem. Commun., 1986,0, 1283-1285
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    Regioselective nucleophilic additions to (η6-benzyl alcohol)tricarbonylchromium: isolation and X-ray crystal structure of the intermediate (η6-5-methylene-6-exo-t-butylcyclohexa-1,3-diene)tricarbonylchromium

    J. Blagg, S. G. Davies, C. L. Goodfellow and K. H. Sutton, J. Chem. Soc., Chem. Commun., 1986, 0, 1283
    DOI: 10.1039/C39860001283

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