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Issue 8, 1986
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Asymmetric Diels–Alder reactions: (S)-(+)-[(η5-C5H5)Fe(CO)(PPh3)COCH[double bond, length half m-dash]CH2] as a chiral acrylate dienophile equivalent

Abstract

The zinc chloride-mediated Diels–Alder reaction between (S)-(+)-[(η5-C5H5)Fe(CO)(PPh3)COCH[double bond, length half m-dash]CH2] and cyclopentadiene yielded (2S)-(–)-bicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid which was converted into the corresponding optically pure iodolactone.

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Article type: Paper
DOI: 10.1039/C39860000609
Citation: J. Chem. Soc., Chem. Commun., 1986,0, 609-610
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    Asymmetric Diels–Alder reactions: (S)-(+)-[(η5-C5H5)Fe(CO)(PPh3)COCH[double bond, length half m-dash]CH2] as a chiral acrylate dienophile equivalent

    S. G. Davies and J. C. Walker, J. Chem. Soc., Chem. Commun., 1986, 0, 609
    DOI: 10.1039/C39860000609

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