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Issue 8, 1986
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Determination of the absolute configuration and optical purity of [(η5-C5H5)Fe(CO)(PPh3)COMe]; X-ray crystal structure of (R)-{(η5-C5H5)Fe(CO)(PPh3)COCH2CH2O[(R)-menthyl]}

Abstract

The enantiomeric purities of (R)-(–)-[(η5-C5H5)Fe(CO)(PPh3)COMe](1)[α]54622–288°(c 0.04, C6H6) and S-(+)-(1)[α]54622+288°(c 0.04, C6H6) are established by two independent methods and the absolute configurations assigned by an X-ray structure analysis of (R)-{(η5-C5H5)Fe(CO)(PPh3)COCH2CH2O [(R)-menthyl]}.

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Article type: Paper
DOI: 10.1039/C39860000607
Citation: J. Chem. Soc., Chem. Commun., 1986,0, 607-609
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    Determination of the absolute configuration and optical purity of [(η5-C5H5)Fe(CO)(PPh3)COMe]; X-ray crystal structure of (R)-{(η5-C5H5)Fe(CO)(PPh3)COCH2CH2O[(R)-menthyl]}

    S. G. Davies, I. M. Dordor-Hedgecock, K. H. Sutton, J. C. Walker, C. Bourne, R. H. Jones and K. Prout, J. Chem. Soc., Chem. Commun., 1986, 0, 607
    DOI: 10.1039/C39860000607

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