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Issue 6, 1986
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The stereoselective synthesis of (–)-(8R)-methylcanadine via selective monocomplexation of canadine to chromium tricarbonyl

Abstract

Regiospecific complexation of the dimethoxy arene ring of (–)-canadine to chromium tricarbonyl, protection of the C-11 position, followed by stereoselective substitution at C-8 effects, after deprotection and decomplexation, a stereoselective synthesis of (–)-(8R)-methylcanadine; a comparison is made with a racemic sample synthesised by an alternative route.

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Article type: Paper
DOI: 10.1039/C39860000492
Citation: J. Chem. Soc., Chem. Commun., 1986,0, 492-493
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    The stereoselective synthesis of (–)-(8R)-methylcanadine via selective monocomplexation of canadine to chromium tricarbonyl

    J. Blagg and S. G. Davies, J. Chem. Soc., Chem. Commun., 1986, 0, 492
    DOI: 10.1039/C39860000492

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