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Issue 4, 1986
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Conversion of WVIOS32– into [WV2O2(µ-S)2(S2)2]2– and vice-versa by internal redox processes induced by I2 and Sx2–

Abstract

Reaction of [NH4]2[WVIOS3](1) with elemental iodine in aqueous solution leads to [WV2O2(µ-S)2(S2)2]2–, isolable as the [NEt4]+ salt (2) which is converted back into (1) by Sx2–, via induced electron-transfer processes.

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Article type: Paper
DOI: 10.1039/C39860000324
Citation: J. Chem. Soc., Chem. Commun., 1986,0, 324-325
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    Conversion of WVIOS32– into [WV2O2(µ-S)2(S2)2]2– and vice-versa by internal redox processes induced by I2 and Sx2–

    S. Sarkar and M. A. Ansari, J. Chem. Soc., Chem. Commun., 1986, 0, 324
    DOI: 10.1039/C39860000324

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