Ab initio molecular orbital calculations suggest that protonated β-halogenoethyl radicals have an unsymmetrically bridged, nonclassical structure, in contrast to their neutral counterparts, which are predicted to be significantly more basic than the corresponding halogenoethanes.
T. Clark and M. C. R. Symons, J. Chem. Soc., Chem. Commun., 1986, 96 DOI: 10.1039/C39860000096
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