SCHEDULED MAINTENANCE
The bis(methoxycarbonyl)tetrachlorobornadienone dimethyl acetal (1) rearranges spontaneously to the hemimellite (2)via the norcaradiene intermediate (6); the corresponding anhydride (5) is stable below 200 °C because steric strain prevents its conversion into a analogous into an analogous intermediate (9).
D. E. Sunko, Z. Lovrić and H. Vančik, J. Chem. Soc., Chem. Commun., 1985, 1589 DOI: 10.1039/C39850001589
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