Jump to main content
Jump to site search

Issue 20, 1985
Previous Article Next Article

Chiral discrimination in the reaction of the enolate [(η5-C5H5)Fe(CO)(PPh3)(COCH2)]Li+ with monosubstituted epoxides: X-ray crystal structure of (RS,SR)-[(η5-C5H5)Fe(CO)(PPh3){COCH2CH2CH(OH)Me}]

Abstract

In the presence of Et2AICI, the lithium enolate derived form the iron acetyl complex [(η5-C5H5)Fe(CO)(PPh3)(COMe)] discriminates between the enantiomers of monosubstituted epoxides to produce essentially only one product diastereoisomer, for example(RS,SR)-[(η5C5H5)Fe(CO)(PPh3){COCH2CH2CH(OH)Me}] in the case of propene oxide.

Back to tab navigation

Article type: Paper
DOI: 10.1039/C39850001446
Citation: J. Chem. Soc., Chem. Commun., 1985,0, 1446-1447
  •   Request permissions

    Chiral discrimination in the reaction of the enolate [(η5-C5H5)Fe(CO)(PPh3)(COCH2)]Li+ with monosubstituted epoxides: X-ray crystal structure of (RS,SR)-[(η5-C5H5)Fe(CO)(PPh3){COCH2CH2CH(OH)Me}]

    S. L. Brown, S. G. Davies, P. Warner, R. H. Jones and K. Prout, J. Chem. Soc., Chem. Commun., 1985, 0, 1446
    DOI: 10.1039/C39850001446

Search articles by author

Spotlight

Advertisements