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Issue 9, 1985
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4-Substituted N-methyl-1,2,3,4-tetrahydroisoquinolines: synthesis via stereoselective substitution of tricarbonyl(N-methyl-1,2,3,4-tetrahydroisoquinoline)chromium

Abstract

Tricarbonyl(N-methyl-1,2,3,4-tetrahydroisoquinolines)chromium undergoes stereoselective 4-exo-deprotonation and subsequent electrophilic additions to generate the corresponding 4-exo-derivatives which after decomplexation yield 4-alkyl-, 4-phenyl-, and 4-hydroxy-N-methyl-1,2,3,4- tetrahydroisoquinolines.

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Article type: Paper
DOI: 10.1039/C39850000619
Citation: J. Chem. Soc., Chem. Commun., 1985,0, 619-620
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    4-Substituted N-methyl-1,2,3,4-tetrahydroisoquinolines: synthesis via stereoselective substitution of tricarbonyl(N-methyl-1,2,3,4-tetrahydroisoquinoline)chromium

    J. Blagg, S. G. Davies and B. E. Mobbs, J. Chem. Soc., Chem. Commun., 1985, 0, 619
    DOI: 10.1039/C39850000619

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