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Issue 4, 1985
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Stereocontrolled tandem alkylations: Michael additions and subsequent alkylations of α,β-unsaturated acyl ligands bound to [(η5-C5H5)Fe(CO)(PPh3)]

Abstract

α,β-Unsaturated acyl complexes of [(η5-C5H5)Fe(CO)(PPh3)] can be prepared by the Peterson olefination reaction and are found to undergo tandem stereoselective Michael additions and subsequent methylations which result in the stereocontrolled synthesis of α- and β-substituted iron acyl complexes.

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Article type: Paper
DOI: 10.1039/C39850000209
Citation: J. Chem. Soc., Chem. Commun., 1985,0, 209-210
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    Stereocontrolled tandem alkylations: Michael additions and subsequent alkylations of α,β-unsaturated acyl ligands bound to [(η5-C5H5)Fe(CO)(PPh3)]

    S. G. Davies and J. C. Walker, J. Chem. Soc., Chem. Commun., 1985, 0, 209
    DOI: 10.1039/C39850000209

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