A biomimetically patterned synthesis of the novel oxazine-fused dehydronoraporphine alkaloid, duguenaine, which proceeds in three steps from an isoquinoline enamide has been developed. The reactions leading to the natural product are general and yield equivalent structures with more highly substituted dehydronoraporphines.
G. R. Lenz and F. J. Koszyk, J. Chem. Soc., Perkin Trans. 1, 1984, 1273 DOI: 10.1039/P19840001273
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