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Issue 5, 1984
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A convenient synthesis of [Ru(η-C5H5)(PPh3)(CO)Cl] and the cations [Ru(η-C5H5)(PPh3)L(CO)]+[L = CO, PMe3, or P(OPh)3]

Abstract

Treatment of [Ru(η-C5H5)(PPh3)2Cl] with sulphur under carbon monoxide at 1–3 atm in hot toluene gives quantitative yields of [Ru(η-C5H5)(PPh3)(CO)Cl], which can be further treated in warm methanol with CO, PMe3, and P(OPh)3 to give the cations [Ru(ηC5H5)(PPh3)(CO)2]+, [Ru(η-C5H5)(PPh3)(PMe3)(CO)]+, and [Ru(η-C5H5)(PPh3){P(OPh)3}(CO)]+ respectively.

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Article type: Paper
DOI: 10.1039/DT9840000993
Citation: J. Chem. Soc., Dalton Trans., 1984,0, 993-994
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    A convenient synthesis of [Ru(η-C5H5)(PPh3)(CO)Cl] and the cations [Ru(η-C5H5)(PPh3)L(CO)]+[L = CO, PMe3, or P(OPh)3]

    S. G. Davies and S. J. Simpson, J. Chem. Soc., Dalton Trans., 1984, 0, 993
    DOI: 10.1039/DT9840000993

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