Application of chiral lanthanide-induced shift reagents to optically active cations: the use of tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorato]europium(III) to determine the enantiomeric purity of tris(phenanthroline)ruthenium(II) dichloride

Jacqueline K. Barton; James S. Nowick

doi:10.1039/C39840001650

This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.

skip RSC | ChemSpider | Feedback

Home > Journals > Journal of the Chemical... > Application of chiral l...

For Authors & Referees | For Librarians | For Members

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Journal of the Chemical Society, Chemical Communications

Issue 24, 1984

Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

Journal Home

Previous Article | Next Article

Paper

Application of chiral lanthanide-induced shift reagents to optically active cations: the use of tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorato]europium(III) to determine the enantiomeric purity of tris(phenanthroline)ruthenium(II) dichloride

Jacqueline K. Barton and James S. Nowick

J. Chem. Soc., Chem. Commun., 1984, 1650-1652

DOI: 10.1039/C39840001650

Please wait while Download options loads

Download Citation

Request Permissions

Abstract
Cited by
Related Content

In non-polar solvents, chiral europium complexes provide attractive n. m. r. shift reagents to resolve spectra of optically active cations, and, in particular, for tris(phenanthroline)ruthenium dichloride,¹H n. m. r. shift differences of up to 0.7 p.p.m. between isomers easily permit the determination of absolute enantiomeric purity.

Journal of the Chemical Society, Chemical Communications - Information Point

Terms & Conditions|Privacy and Cookies |Accessibility|ACAP Enabled

Journal of the Chemical Society, Chemical Communications

Application of chiral lanthanide-induced shift reagents to optically active cations: the use of tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorato]europium(III) to determine the enantiomeric purity of tris(phenanthroline)ruthenium(II) dichloride

Log in (Free Access)

Log in (Subscriber Access)

Search Articles By

Journal of the Chemical Society, Chemical Communications

Application of chiral lanthanide-induced shift reagents to optically active cations: the use of tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorato]europium(III) to determine the enantiomeric purity of tris(phenanthroline)ruthenium(II) dichloride

This text is added as a work around for heading error in Accessibility testing

Log in (Free Access)

Log in (Subscriber Access)

Search Articles By