The crystal structures of 1,6-diazabicyclo[4.4.4]tetradecane (1) and of its inside-protonated ion (2), which were originally described in space group C2/c, should be described instead in trigonal space groups, (1) in Rc and (2) in Pc; both moieties have crystallographically imposed point symmetry D3 rather than C2.
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Journal of the Chemical Society, Chemical Communications
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