Pyrano[3,4-b]indol-3-ones (5), synthetic equivalents of indole-2,3-quinodimethanes, undergo Deils–Alder reaction with acetylenes and with benzyne to give carbazoles and benzo[b]carbozoles respectively.
C. J. Moody, J. Chem. Soc., Chem. Commun., 1984, 925 DOI: 10.1039/C39840000925
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