Selective total synthesis of (±)-α- and γ-polypodatetraene

Mugio Nishizawa; Hisaya Nishide; Yuji Hayashi

doi:10.1039/C39840000467

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Selective total synthesis of (±)-α- and γ-polypodatetraene

Mugio Nishizawa, Hisaya Nishide and Yuji Hayashi

Abstract

The fern metabolites, α-and γ-polypodatetraene, possible biosynthetic intermediates of onocerane type triterpenoids, are selectively synthesized by mercury(II) trifluoromethanesulphonate–amine complex-induced olefin cyclization followed by simple chemical transformations.

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DOI: https://doi.org/10.1039/C39840000467
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1984, 467-468

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Selective total synthesis of (±)-α- and γ-polypodatetraene

M. Nishizawa, H. Nishide and Y. Hayashi, J. Chem. Soc., Chem. Commun., 1984, 467 DOI: 10.1039/C39840000467

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Journal of the Chemical Society, Chemical Communications

Selective total synthesis of (±)-α- and γ-polypodatetraene

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Selective total synthesis of (±)-α- and γ-polypodatetraene

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