Cyclisation of 3-methylcyclohex-2-enones and the derived epoxides containing alkene, alkyne, and aryl side-chains yields bicyclo[4.4.0]decane derivatives when the alkene or alkyne is electronically biased towards six-membered ring formation and when the alkene is electronically unbiased.
J. A. Amupitan, E. Huq, M. Mellor, E. G. Scovell and J. K. Sutherland, J. Chem. Soc., Perkin Trans. 1, 1983, 751 DOI: 10.1039/P19830000751
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