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Issue 21, 1983
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Stereochemical control and mechanistic aspects of the alkylation of [(η5-C5H5)Fe(L)(CO)(COCHR)]Li+(L = PPh3, PPh2NEt2; R = Me, Et): X-ray crystal structure of [(η5-C6H5)Fe(PPh3)(CO){COCH(Me)Et}]

Abstract

Determination of the molecular structure of [(η5-C5H5)Fe(PPh3)(CO){COCH(Me)Et}], formed in the diastereoselective methylation of [(η5-C5H5)Fe(PPh3)(CO)(COCHEt)]Li+, allows the assignment of the relative configuration of the new chiral centre and indicates the origin of the high diastereoselectivities observed in this type of reaction.

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Article type: Paper
DOI: 10.1039/C39830001202
Citation: J. Chem. Soc., Chem. Commun., 1983,0, 1202-1203
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    Stereochemical control and mechanistic aspects of the alkylation of [(η5-C5H5)Fe(L)(CO)(COCHR)]Li+(L = PPh3, PPh2NEt2; R = Me, Et): X-ray crystal structure of [(η5-C6H5)Fe(PPh3)(CO){COCH(Me)Et}]

    G. J. Baird, J. A. Bandy, S. G. Davies and K. Prout, J. Chem. Soc., Chem. Commun., 1983, 0, 1202
    DOI: 10.1039/C39830001202

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