Energetic 11C(1D) atoms insert into the double bond of ethylene to yield [2-11C]allene, while the corresponding reaction with thermalized 11C(1D) atoms will not proceed; on the other hand, 11C(3p) atoms undergo both double bond and C–H insertion to yield [2-11C]- and [1-11C]allenes, respectively.
R. A. Ferrieri, A. P. Wolf and Y. Tang, J. Chem. Soc., Chem. Commun., 1982, 124 DOI: 10.1039/C39820000124
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