Iodine has a marked catalytic effect on the thermolysis of azidocinnamates; indoles, isoquinolines, 1,2-dihydroisoquinolines, or enamines are isolated depending on the conditions.
D. M. B. Hickey, C. J. Moody and C. W. Rees, J. Chem. Soc., Chem. Commun., 1982, 3 DOI: 10.1039/C39820000003
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