SCHEDULED MAINTENANCE
The ten-vertex palladium cluster Pd10(CO)12[PBun3]6 obtained by treatment of Pd(OAc)2 with PBun3 and CO [molar ratio Pd : P 1 : 4·5], is shown by X-ray crystallography to contain a tetracapped octahedron of metal atoms, i.e. a distorted fragment of close packing Pd10 with 16 skeletal electrons.
E. G. Mednikov, N. K. Eremenko, V. A. Mikhailov, S. P. Gubin, Y. L. Slovokhotov and Y. T. Struchkov, J. Chem. Soc., Chem. Commun., 1981, 989 DOI: 10.1039/C39810000989
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