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Issue 4, 1980
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Hydride reduction of the cation [(η5-C5H5)Fe(triphos)]PF6: direct nucleophilic attack on the metal, and hydrogen exchange in the product hydride (η5-C5H5)FeH(triphos)(triphos = Ph2PCH2CH2PPhCH2CH2PPh2)

Abstract

Reduction of the cation [(η5-C5H5)Fe(triphos)]PF6 with lithium aluminium deuteride gives (η5-C5H5)FeD(triphos) which slowly undergoes H–D scrambling at 20 °C (triphos = Ph2PCH2CH2PPhCH2CH2PPh2).

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Article type: Paper
DOI: 10.1039/C39800000159
Citation: J. Chem. Soc., Chem. Commun., 1980,0, 159-160
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    Hydride reduction of the cation [(η5-C5H5)Fe(triphos)]PF6: direct nucleophilic attack on the metal, and hydrogen exchange in the product hydride (η5-C5H5)FeH(triphos)(triphos = Ph2PCH2CH2PPhCH2CH2PPh2)

    S. G. Davies, H. Felkin and O. Watts, J. Chem. Soc., Chem. Commun., 1980, 0, 159
    DOI: 10.1039/C39800000159

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