Additions of some iodine based electrophilic reagents to 1-trimethylsilylcyclohexene (1), and its 4-t-butyl derivative, occur with high regio- and stereoselectivity to give adducts in which iodine is attached to C-1 (2 and 5): these adducts have been transformed into a number of functionalised silanes.
E. J. Thomas and G. H. Whitham, J. Chem. Soc., Chem. Commun., 1979, 212 DOI: 10.1039/C39790000212
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