SCHEDULED MAINTENANCE
Indane 3a,7a-oxide (1) is isomerised on heating to indane 3a,4-oxide (2). A number of attempts to prepare the latter from 3a,6-dihydroindanes were unsuccessful, but a preparation from 10-oxatricyclo[4.3.1.01,6]dec-3-ene provided confirmation of the assigned structure (2).
S. G. Davies and G. H. Whitham, J. Chem. Soc., Perkin Trans. 1, 1978, 1479 DOI: 10.1039/P19780001479
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