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Issue 11, 1978
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Inorganic Grignard reagents. Preparations and reactions of [bromobis(tetrahydrofuran)magnesio]bis(η-cyclopentadienyl) hydridomolybdenum

Abstract

The compound [Mo(η-C5H5)2H{MgBr(thf)2}] is described. It reacts with CO2, PhCH2Br, C3H5Br, MeI, and MeCOCl to give [Mo(η-C5H5)2(CO)], [Mo(η-C5H5)2(CH2Ph)2], [Mo(η-C3H5)(η-C5H5)2][PF6], [Mo(η-C5H5)2HI], Mo(η-C5H5)2(COMe)H], and [Mo(η-C5H5)2(COMe)2] respectively. Reaction paths for these products are discussed.

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Article type: Paper
DOI: 10.1039/DT9780001510
Citation: J. Chem. Soc., Dalton Trans., 1978,0, 1510-1514
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    Inorganic Grignard reagents. Preparations and reactions of [bromobis(tetrahydrofuran)magnesio]bis(η-cyclopentadienyl) hydridomolybdenum

    S. G. Davies and M. L. H. Green, J. Chem. Soc., Dalton Trans., 1978, 0, 1510
    DOI: 10.1039/DT9780001510

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