A new conformational effect, the predominance of the axial conformation in 4-methoxy- and 4-acetoxy-derivatives of spiro[5.2]octane, is reported, and its origin is discussed in terms of orbital interaction together with charge transfer and steric repulsion.
N. S. Zefirov, E. G. Chalenko, A. V. Aripovsky, I. G. Mursakulov, M. M. Guseinov and E. A. Ramazanov, J. Chem. Soc., Chem. Commun., 1978, 147 DOI: 10.1039/C39780000147
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