Order–disorder transitions in 1- and 2-methyladamantane, 1,3-dimethyladamantane, 1,3,5-trimethyladamantane, 1,3,5,7-tetramethyladamantane and in the 1-halogenoadamantanes have been investigated by differential scanning calorimetry. The effects of substituent groups on the disordered phase behaviour of these molecules are discussed.
T. Clark, T. Mc. O. Knox, H. Mackle and M. A. McKervey, J. Chem. Soc., Faraday Trans. 1, 1977, 73, 1224 DOI: 10.1039/F19777301224
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