SCHEDULED MAINTENANCE
A procedure is described for the conversion of six-membered ring allylic bromides via the corresponding nitriles into βγ-unsaturated acids and esters. In this way cis- and trans-5-t-butylcyclohex-2-enecarboxylic acids have been prepared. Configurations of the latter are assigned on the basis of hydrogenation to the known saturated acids.
S. G. Davies and G. H. Whitham, J. Chem. Soc., Perkin Trans. 1, 1976, 2279 DOI: 10.1039/P19760002279
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