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Issue 21, 1976
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A convenient synthesis of βγ-unsaturated carboxylic acids and esters. The isomeric 5-t-butylcyclohex-2-enecarboxylic acids

Abstract

A procedure is described for the conversion of six-membered ring allylic bromides via the corresponding nitriles into βγ-unsaturated acids and esters. In this way cis- and trans-5-t-butylcyclohex-2-enecarboxylic acids have been prepared. Configurations of the latter are assigned on the basis of hydrogenation to the known saturated acids.

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Article type: Paper
DOI: 10.1039/P19760002279
Citation: J. Chem. Soc., Perkin Trans. 1, 1976,0, 2279-2280
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    A convenient synthesis of βγ-unsaturated carboxylic acids and esters. The isomeric 5-t-butylcyclohex-2-enecarboxylic acids

    S. G. Davies and G. H. Whitham, J. Chem. Soc., Perkin Trans. 1, 1976, 0, 2279
    DOI: 10.1039/P19760002279

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