Issue 11, 1976

Rearrangement of ortho-blocked N-arylbenzimidoyl nitrenes. A proposed [1,9] methyl migration

Abstract

The pyrimidines (4) are isolated from the products of photolysis of the sulphimides (1) and of the tetrazoles (2); pyrolysis of the tetrazoles gives benzimidazoles (5) in addition to the pyrimidines, the formation of these products being rationalised by mechanisms involving successive [1,5] or [1,9] shifts in 3aH-benzimidazole intermediates.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 414-415

Rearrangement of ortho-blocked N-arylbenzimidoyl nitrenes. A proposed [1,9] methyl migration

T. L. Gilchrist, C. J. Moody and C. W. Rees, J. Chem. Soc., Chem. Commun., 1976, 414 DOI: 10.1039/C39760000414

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements