Issue 11, 1976

Direct formation, and reactions of a carbonyl anion free from competitive nucleophiles

Abstract

At low temperature, in tetrahydrofuran (THF)–ether-pentane, ButLi abstracts a proton from bis(isopropyl)formamide to give LiCONPri2, which reacts with carbonyl compounds to give high yields of α-hydroxyamides.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 387-388

Direct formation, and reactions of a carbonyl anion free from competitive nucleophiles

K. Smith and K. Swaminathan, J. Chem. Soc., Chem. Commun., 1976, 387 DOI: 10.1039/C39760000387

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