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Protonation of trialkylcyanoborates in bis-(2-methoxyethyl) ether (diglyme) leads to migration of two alkyl groups from boron to carbon and the production of derivatives of 1,4-diaza-2,5-diboracyclohexane. On oxidation, these compounds yield ketones.
A. Pelter, M. G. Hutchings and K. Smith, J. Chem. Soc., Perkin Trans. 1, 1975, 142 DOI: 10.1039/P19750000142
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