Issue 15, 1974

Nitration of 3-iodoanisole and 2,6-dimethyl-4-iodoanisole

Abstract

Nitration of 3-iodoanisole in the presence of nitrous acid was found to give 3-nitroanisole, 3-iodo-4-nitroanisole, and 3,6-di-iodo-4-nitroanisole. Nitration of 2,6-dimethyl-4-iodoanisole was found to result in the displacement of iodine. The rate of reaction was studied as a function of nitrous acid concentration and acidity. The results confirm the mechanism for nitrodeiodination proposed previously.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1974, 1784-1785

Nitration of 3-iodoanisole and 2,6-dimethyl-4-iodoanisole

A. R. Butler and A. P. Sanderson, J. Chem. Soc., Perkin Trans. 2, 1974, 1784 DOI: 10.1039/P29740001784

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