Perfluoro-t-butoxyl radicals differ from t-butoxyl radicals in that they add to double bonds rather than abstract allylic hydrogens, and abstract hydrogen from the alkyl groups of trialkyl phosphites or trialkyl-boranes in preference to exclusive attack at the metal centre.
A. G. Davies, R. W. Dennis, B. P. Roberts and R. C. Dobbie, J. Chem. Soc., Chem. Commun., 1974, 468 DOI: 10.1039/C39740000468
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