Anharmonicity data derived from observed hot band structure for the ν7 fundamental of VF5 has resulted in a 1.8 kcal/mol (7.7 kJ mol–1) barrier associated with the intramolecular ligand exchange process.
R. R. Holmes, L. S. Couch and C. J. Hora, J. Chem. Soc., Chem. Commun., 1974, 175 DOI: 10.1039/C39740000175
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